MATERIAL SAFETY DATA SHEET

ALCO PRODUCTS LLC Dated: September 22, 2009

580 ST JEAN

DETROIT MI 48214-3476

313-823-7500

FAX: 313-331-4726

24 HOUR EMERGENCY TELEPHONE: 800-424-9300 (CHEMTREC)

PRODUCT: #207 Spray Primer

SECTION 1 PRODUCT IDENTIFICATION

Trade Name: Asphalt Primer

Hazardous Rating: 1 – Health 4 – Fire 0 – Reactivity

(0 = Least; 4 = Extreme)

SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS

Item Chemical Name CAS Number WT/WT %

Less Than

01 Asphalt 8052-42-4 35.0 %

02 2-Propanone 67-64-1 30.0 %

03 Propane/Isobutane/N-Butane 68476-86-8 20.0 %

04 Stoddard Solvent 80152-41-3 15.0 %

05 Propane/Isobutane/N-Butane 68476-86-8 10.0 %

EXPOSURE LIMITS

ACGIH OSHA COMPANY

Item TLV-TWA TLV-STEL PEL-TWA PEL-Ceiling TLV-TWA SKIN

01 5 Mg/M³ N.E N.E. N.E. N.E. No

02 750 PPM 1000 PPM 750 PPM N.E. N.E. No

03 800 PPM N.E. 800 PPM N.E. N.E. Yes

04 100 PPM N.E. 100 PPM N.E. N.E. No

05 800 PPM N.E. 800 PPM N.E. N.E. Yes

N.E. = Not Established

SECTION 3 PHYSICAL/CHEMICAL DATA

Boiling Range: -43° - 387° F.

Vapor Density: Heavier than air

Specific Gravity: 0.7708

Evaporation Rate: Faster than Butyl Acetate

Vapor Pressure: 45 – 55

Soluble in Water: Nil

Appearance: Black liquid, solvent odor

SECTION 4 FIRE & EXPLOSION DATA

Flash Point: -4° F.

Upper Explosive Limit (UEL): 12.8%

Lower Explosive Limit (LEL): 0.7%

Sensitive to Static Discharge: No

Extinguishing Media: alcohol Foam, CO₂, Dry Chemical, Foam, Water Fog

Unusual Fire & Explosion Hazards: Vapors can travel to a source of ignition and flash back. “Empty”

containers retain product residue (liquid and/or vapor) and can be dangerous DO NOT PRESSURIZE,

CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME,
SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE, CAUSE
INJURY OR DEATH.

Special Firefighting Procedures: Containers can build up pressure if exposed to heat (fire). As in any fire,
wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and
full protective gear.

SECTION 5 STABILITY/REACTIVITY DATA

Conditions to Avoid: All sources of ignition, welding arcs and open flame

Incompatibility: Strong acids, alkalis, oxidizers and amines

Hazardous Decomposition Products: Oxides of carbon, oxides of nitrogen and may produce forms of
chloride, chlorine and phosgene

Hazardous Polymerization: Will not occur under normal conditions

Stability: This product is stable under normal storage conditions

SECTION 6 HEALTH HAZARD DATA

EMERGENCY OVERVIEW: Vapors irritating to eyes and respiratory tract. Vapors may cause flash fire or
explosion.

Primary Routes of Entry: Inhalation, Skin Contact, Ingestion, Eye Contact

Effects of Overexposure:

Inhalation – Headaches, dizziness, nausea, decreased blood pressure, changes in heart rate and
cyanosis may result from over-exposure to vapor or skin exposure. Prolonged inhalation may be
harmful.

Skin Contact – Prolonged or repeated contact can result in defatting and drying of the skin which may
result in skin irritation and dermatitis (rash)

Ingestion – This material maybe harmful or fatal if swallowed. Corrosive and may cause severe and
permanent damage to mouth, throat and stomach.

Eyes – Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening
and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes.

Chronic Hazards: Overexposure may cause nervous system damage. Overexposure may cause lung
damage. Overexposure may cause kidney damage.

SECTION 7 FIRST AID PROCEDURE

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get immediate medical attention.

Skin Contact: Immediately flush skin with plenty of water. Remove clothing. Get medical attention immediately.
Wash clothing separately before reuse.

Ingestion: Get medical attention immediately. If swallowed, DO NOT induce vomiting. Give victim a glass
of water or milk. Call a physician or poison control center immediately. Never give anything by mouth
to an unconscious person.

Eye Contact: Immediately flush eyes with plenty of water. Get medical attention if irritation persists.

SECTION 8 PREVENTATIVE MEASURES/SAFE HANDLING & USE

Leak and Spill Procedure: Use absorbent sweeping material (e.g. dry sand or earth) to soak up material.
Place in a chemical waste container. Dispose as hazardous waste.

Waste Disposal: Dispose in an approved landfill in accordance with applicable Federal, state and local

regulations.

Precautions in Handling & Storage: Wash hands after handling. Store away from heat, sparks, flame.

Keep from freezing.

SECTION 9 CONTROL PROTECTION DATA

Engineering controls: Local exhaust ventilation may be necessary to control any air contaminants to
within their TLV’s during the use of this product.

Respiratory Protection: A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge
or canister may be permissible under certain circumstances where airborne concentrations are
expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a
positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure
levels are not known, or any other circumstances where air purifying respirators may not provide
adequate protection.

Skin Protection: Where contact is likely, wear chemical resistant gloves, a chemical suit, rubber boots
and chemical safety goggles, plus a face shield.

Eye Protection: Wear safety glasses with side shields or goggles and a face shield.

Other Protective Equipment: Standard industrial clothing standards should be followed.

Hygienic Practices: Wash hands before eating. Remove contaminated clothing and wash before reuse.
Use only in a well ventilated area. Follow all MSDS/label precautions even after container is emptied
because they may retain product residues. Avoid prolonged or repeated contact with skin. Avoid
breathing vapors. Avoid contact with eyes, skin and clothing.

KEEP OUT OF REACH OF CHILDREN!

SECTION 10 REGULATORY INFORMATION

us Federal Regulations:

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200)

CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA “Hazard
Categories” promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet
the following categories:

Immediate Health Hazard Chronic Health Hazard

Fire Hazard Pressurized Gas Hazard

SARA Section 313

This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:

No SARA Section 313 components exist in this product

Toxic Substance Control Act:

This product contains the following chemical substances subject to the reporting requirements of
TSCA 12(B) if exported from the United States:

No information is available

US State Regulations:

New Jersey Right-To-Know: The following materials are non-hazardous but are among the top five
components in this product:

No non-hazardous materials are among the top five ingredients

Pennsylvania Right-To-Know: The following non-hazardous ingredients are present in the product at
greater than 3%:

No non-hazardous ingredients are present at greater than 3%

California Proposition 65:

WARNING: The chemical(s) noted below and contained in this product, are knows to the state of
California to cause cancer, birth defects or other reproductive harm:

No Proposition 65 chemicals exist in this product

International Regulations:

Canadian WHMIS: This MSD has been prepared in compliance with Controlled Product Regulations
except for use of the 14 headings.

Canadian WHMIS Class: No information available

SECTION 11 SHIPPING INFORMATION

DOT Proper Shipping Name: Consumer Commodity

DOT Technical name: ORM-D

SECTION 12 USER RESPONSIBILITY

This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product must be informed of the recommended safety precautions and must have access to this information. For any other uses, exposures must be evaluated so that appropriate handling practices and training programs can be established to ensure safe work place operations. Please consult your local sales representative for any further information.

SECTION 13 CLEAN UP AND DISPOSAL

Practice good personal hygiene. Launder contaminated clothing before reuse. Use control protection such as chemical splash proof goggles, chemical resistant gloves, barrier cream. Clean tools and equipment with kerosene, adhering to manufacturer’s precautions. DO NOT USE GASOLINE OR NAPHTHA. Follow proper container management in disposing of containers. CERCLA amendment on disposal of containers should be followed.

SECTION 14 DISCLAIMER

The information set forth herein is believed to be accurate but is not warranted to be, whether originating with ALCO PRODUCTS LLC or not. Recipients are advised to confirm in advance of need that the information is current, applicable and suitable to their circumstances.

This Material Safety Data Sheet supersedes all other previously dated sheets for this product.